A new insight into regulating high energy facets of rutile TiO2

被引:71
作者
Lai, Zhuangchai [1 ]
Peng, Feng [1 ]
Wang, Hongjuan [1 ]
Yu, Hao [1 ]
Zhang, Shanqing [2 ]
Zhao, Huijun [2 ]
机构
[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
[2] Griffith Univ, Griffith Sch Environm, Gold Coast, Qld 4222, Australia
基金
中国国家自然科学基金;
关键词
PHOTOCATALYTIC ACTIVITY; SOLVOTHERMAL SYNTHESIS; SINGLE-CRYSTALS; ANATASE; NANOSHEETS; SURFACES; NANORODS;
D O I
10.1039/c3ta00188a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A facile and controllable hydrothermal approach is developed to synthesize rutile TiO2 single crystals with regulable (110), (111) and (001) facets without toxic capping agents. The normalized surface photoreactivity of the as-prepared TiO2 with (111) and (001) facets is approximately 5 times that of rutile TiO2 with majority (110) facets.
引用
收藏
页码:4182 / 4185
页数:4
相关论文
共 22 条
[1]   Exposed crystal surface-controlled rutile TiO2 nanorods prepared by hydrothermal treatment in the presence of poly(vinyl pyrrolidone) [J].
Bae, Eunyoung ;
Ohno, Teruhisa .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 91 (3-4) :634-639
[2]   Exposed crystal surface-controlled TiO2 nanorods having rutile phase from TiCl3 under hydrothermal conditions [J].
Bae, Eunyoung ;
Murakami, Naoya ;
Ohno, Teruhisa .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 300 (1-2) :72-79
[3]   Nonaqueous Synthesis of TiO2 Nanocrystals Using TiF4 to Engineer Morphology, Oxygen Vacancy Concentration, and Photocatalytic Activity [J].
Gordon, Thomas R. ;
Cargnello, Matteo ;
Paik, Taejong ;
Mangolini, Filippo ;
Weber, Ralph T. ;
Fornasiero, Paolo ;
Murray, Christopher B. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (15) :6751-6761
[4]   Anatase TiO2 Crystals with Exposed High-Index Facets [J].
Jiang, Hai Bo ;
Cuan, Qian ;
Wen, Ci Zhang ;
Xing, Jun ;
Wu, Di ;
Gong, Xue-Qing ;
Li, Chunzhong ;
Yang, Hua Gui .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (16) :3764-3768
[5]   {111}-faceting of low-temperature processed rutile TiO2 rods [J].
Kakiuchi, Keita ;
Hosono, Eiji ;
Imai, Hiroaki ;
Kimura, Toshio ;
Fujihara, Shinobu .
JOURNAL OF CRYSTAL GROWTH, 2006, 293 (02) :541-545
[6]   Low temperature solvothermal synthesis of anatase TiO2 single crystals with wholly {100} and {001} faceted surfaces [J].
Lai, Zhuangchai ;
Peng, Feng ;
Wang, Yun ;
Wang, Hongjuan ;
Yu, Hao ;
Liu, Porun ;
Zhao, Huijun .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (45) :23906-23912
[7]   Synthesis of High-Quality Brookite TiO2 Single-Crystalline Nanosheets with Specific Facets Exposed: Tuning Catalysts from Inert to Highly Reactive [J].
Lin, Haifeng ;
Li, Liping ;
Zhao, Minglei ;
Huang, Xinsong ;
Chen, Xiaomei ;
Li, Guangshe ;
Yu, Richeng .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (20) :8328-8331
[8]   Crystal facet engineering of semiconductor photocatalysts: motivations, advances and unique properties [J].
Liu, Gang ;
Yu, Jimmy C. ;
Lu, Gao Qing ;
Cheng, Hui-Ming .
CHEMICAL COMMUNICATIONS, 2011, 47 (24) :6763-6783
[9]   Anatase TiO2 single crystals with exposed {001} and {110} facets: facile synthesis and enhanced photocatalysis [J].
Liu, Min ;
Piao, Lingyu ;
Zhao, Lei ;
Ju, Siting ;
Yan, Zijie ;
He, Tao ;
Zhou, Chunlan ;
Wang, Wenjing .
CHEMICAL COMMUNICATIONS, 2010, 46 (10) :1664-1666
[10]   Visible light active pure rutile TiO2 photoanodes with 100% exposed pyramid-shaped (111) surfaces [J].
Liu, Xiaolu ;
Zhang, Haimin ;
Yao, Xiangdong ;
An, Taicheng ;
Liu, Porun ;
Wang, Yun ;
Peng, Feng ;
Carroll, Anthony R. ;
Zhao, Huijun .
NANO RESEARCH, 2012, 5 (11) :762-769