An Ion-Pair Template for Rotaxane Formation and its Exploitation in an Orthogonal Interaction Anion-Switchahle Molecular Shuttle

被引：96

作者：

Barrell, Michael J. ^{[1
]}

Leigh, David A. ^{[1
]}

Lusby, Paul J. ^{[1
]}

Slawin, Alexandra M. Z. ^{[2
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 42期

关键词：

anion recognition; molecular shuttles; palladium; rotaxanes; template synthesis;

D O I：

10.1002/anie.200802745

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Chloride control: The serendipitous discovery of a molecular recognition motif that is triggered by the formation of an anion-palladium coordination bond is exploited as an efficient rotaxane-forming template and as the basis of a molecular shuttle. The macrocycle of this rotaxane moves between the two stations when the counterion is changed from chloride to hexafluorophosphate (see picture). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8036 / 8039

页数：4

共 82 条

[1] Novel photoswitchable rotaxanes [J].

Abraham, Werner ;

Buck, Karin ;

Orda-Zgadzaj, Marziena ;

Schmidt-Schaeffer, Sebastian ;

Grummt, Ulrich-W. .

CHEMICAL COMMUNICATIONS, 2007, (29) :3094-3096

[2] Electrochemically switchable hydrogen-bonded molecular shuttles [J].

Altieri, A ;

Gatti, FG ;

Kay, ER ;

Leigh, DA ;

Martel, D ;

Paolucci, F ;

Slawin, AMZ ;

Wong, JKY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (28) :8644-8654

[3] Remarkable positional discrimination in bistable light- and heat-switchable hydrogen-bonded molecular shuttles [J].

Altieri, A ;

Bottari, G ;

Dehez, F ;

Leigh, DA ;

Wong, JKY ;

Zerbetto, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (20) :2296-2300

[4]

Altieri A., 2003, ANGEW CHEM, V115, P2398

[5] A clicked bistable [2]rotaxane [J].

Aprahamian, Ivan ;

Dichtel, William R. ;

Ikeda, Taichi ;

Heath, James R. ;

Stoddart, J. Fraser .

ORGANIC LETTERS, 2007, 9 (07) :1287-1290

[6] Rotaxanes incorporating two different coordinating units in their thread:: Synthesis and electrochemically and photochemically induced molecular motions [J].

Armaroli, N ;

Balzani, V ;

Collin, JP ;

Gaviña, P ;

Sauvage, JP ;

Ventura, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) :4397-4408

[7] Acid-base controllable molecular shuttles [J].

Ashton, PR ;

Ballardini, R ;

Balzani, V ;

Baxter, I ;

Credi, A ;

Fyfe, MCT ;

Gandolfi, MT ;

Gómez-López, M ;

Martínez-Díaz, MV ;

Piersanti, A ;

Spencer, N ;

Stoddart, JF ;

Venturi, M ;

White, AJP ;

Williams, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (46) :11932-11942

[8] Catalytic "Active-Metal" template synthesis of [2]rotaxanes, [3]rotaxanes, and molecular shuttles, and some observations on the mechanism of the Cu(I)-catalyzed azide-alkyne 1,3-cycloaddition [J].

Aucagne, Vincent ;

Berna, Jose ;

Crowley, James D. ;

Goldup, Stephen M. ;

Haenni, Kevin D. ;

Leigh, David A. ;

Lusby, Paul J. ;

Ronaldson, Vicki E. ;

Slawin, Alexandra M. Z. ;

Viterisi, Aurlien ;

Walker, D. Barney .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (39) :11950-11963

[9] Autonomous artificial nanomotor powered by sunlight [J].

Balzani, V ;

Clemente-León, M ;

Credi, A ;

Ferrer, B ;

Venturi, M ;

Flood, AH ;

Stoddart, JF .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (05) :1178-1183

[10] A LIGHT-INDUCED MOLECULAR SHUTTLE BASED ON A [2]ROTAXANE-DERIVED TRIAD [J].

BENNISTON, AC ;

HARRIMAN, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (10) :1459-1461

← 1 2 3 4 5 6 7 8 9 →