Synthesis of a nanocrystalline composite W-25 wt.%Ag powder by high energy milling

被引：15

作者：

Alves da Costa, Francine ^{[1
]}

Giuseppe Pereira da Silva, Angelus ^{[2
]}

Ambrozio Filho, Francisco ^{[3
]}

Gomes, Uilame Umbelino ^{[4
]}

Vieira, Francisco Antonio ^{[5
]}

机构：

[1] Univ Fed Rio Grande do Norte, Lab Mat Ceram & Metais Especiais, BR-59072970 Natal, RN, Brazil

[2] UENF, Lab Mat Avancados, BR-28015620 Campos Dos Goytacazes, RJ, Brazil

[3] IPEN CNEN SP, Lab Met Po, BR-05508900 Sao Paulo, Brazil

[4] Univ Fed Rio Grande do Norte, Dept Fis Teor & Expt, BR-59072970 Natal, RN, Brazil

[5] CTGas, Lab Ensaios Mat, BR-59063400 Natal, RN, Brazil

来源：

POWDER TECHNOLOGY | 2008年 / 188卷 / 01期

关键词：

High energy milling; Nanostructured W-Ag composite powder; W-Ag pseudo alloy;

D O I：

10.1016/j.powtec.2008.03.009

中图分类号：

TQ [化学工业];

学科分类号：

0817 [化学工程与技术];

摘要：

W-Ag pseudo-alloys are used in electric contacts of circuit breakers. They are produced by sintering of W-Ag powder mixtures followed by hot pressing or rolling to increase density. High energy milling (HEM) can enhance sintering of systems that present low sinterability because it improves dispersion, promotes refinement of the phases and produces composite particles. This work investigates the effect of HEM upon a W-25 wt.%Ag powder mixture. Phase dispersion, evolution of the shape and size of the particles during milling and the influence of strain on the crystal structure are investigated. The milled powders consist of composite particles that were formed in the first 25 h of milling. Longer milling times improve the distribution of phases inside the composite particles. The formation of the composite particles involves sequential steps of deformation, fragmentation, cold welding, work hardening and piercing of particles of the hard phase in the soft phase. The crystal lattice of W and Cu is damaged, but is not amorphized. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：30 / 33

页数：4

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