First evidence of che LIESST effect in a Langmuir-Blodgett film

被引：64

作者：

Létard, JF

Nguyen, O

Soyer, H

Mingotaud, C

Delhaès, P

Kahn, O

机构：

[1] Inst Chim Matiere Condensee Bordeaux, Lab Sci Mol, UPR CNRS 9048, F-33608 Pessac, France

[2] Ctr Rech Paul Pascal, UPR CNRS 8641, F-33600 Pessac, France

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 13期

关键词：

D O I：

10.1021/ic990259m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The LIESST effect has been observed for an iron(II) compound organized in Langmuir-Blodgett (LB) architecture. Both the LIESST population and relaxation are faster for the LB film than for the powder. These results can be related to the high optical quality of the LB films and the intensity pressure effect induced by the surroundings.

引用

收藏

页码：3020 / +

页数：3

相关论文

共 27 条

[1] LANGMUIR-BLODGETT-FILMS OF SPIN TRANSITION IRON(II) METALLOORGANIC POLYMERS .1. IRON(II) COMPLEXES OF OCTADECYL-1,2,4-TRIAZOLE [J].

ARMAND, F ;

BADOUX, C ;

BONVILLE, P ;

RUAUDELTEIXIER, A ;

KAHN, O .

LANGMUIR, 1995, 11 (09) :3467-3472

[2] LIGHT-INDUCED EXCITED-SPIN-STATE TRAPPING IN IRON(II) SPIN-CROSSOVER SYSTEMS - OPTICAL SPECTROSCOPIC AND MAGNETIC-SUSCEPTIBILITY STUDY [J].

DECURTINS, S ;

GUTLICH, P ;

HASSELBACH, KM ;

HAUSER, A ;

SPIERING, H .

INORGANIC CHEMISTRY, 1985, 24 (14) :2174-2178

[3] SPIN TRANSITIONS IN 6-COORDINATE IRON(II) COMPLEXES [J].

GOODWIN, HA .

COORDINATION CHEMISTRY REVIEWS, 1976, 18 (03) :293-325

[4] Structural approach of the features of the spin crossover transition in iron(II) compounds [J].

Guionneau, P ;

Létard, JF ;

Yufit, DS ;

Chasseau, D ;

Bravic, G ;

Goeta, AE ;

Howard, JAK ;

Kahn, O .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (04) :985-994

[5]

Gutlich P, 1996, NATO ADV SCI INST SE, V321, P327

[6]

GUTLICH P, 1981, STRUCT BOND, V44, P83

[7] THERMAL AND OPTICAL SWITCHING OF IRON(II) COMPLEXES [J].

GUTLICH, P ;

HAUSER, A ;

SPIERING, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (20) :2024-2054

[8]

GUTLICH P, 1991, STRUCT BONDING BERLI, V76, P51

[9] REVERSIBILITY OF LIGHT-INDUCED EXCITED SPIN STATE TRAPPING IN THE FE(PTZ)6(BF4)2 AND THE ZN1-XFEX(PTZ)6(BF4)2 SPIN-CROSSOVER SYSTEMS [J].

HAUSER, A .

CHEMICAL PHYSICS LETTERS, 1986, 124 (06) :543-548

[10] LIGHT-INDUCED EXCITED SPIN STATE TRAPPING (LIESST) IN [FE(2-MEPHEN)3]2+ EMBEDDED IN POLYMER MATRICES [J].

HAUSER, A ;

ADLER, J ;

GUTLICH, P .

CHEMICAL PHYSICS LETTERS, 1988, 152 (06) :468-472