Synthesis, catalytic activity and redox properties of palladium(0) complexes with 15-membered triolefinic macrocyclic ligands containing one, two or three ferrocenyl groups

被引:27
作者
Llobet, A
Masllorens, E
Moreno-Mañas, M
Pla-Quintana, A
Rodríguez, M
Roglans, A
机构
[1] Univ Girona, Dept Chem, Girona 17071, Spain
[2] Univ Autonoma Barcelona, Dept Chem, Barcelona 08193, Spain
关键词
macrocycles; ferrocene; triene palladium(0) complexes; catalysis;
D O I
10.1016/S0040-4039(02)00028-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A series of 15-membered triolefinic macrocycles containing ferrocenyl groups and their palladium(0) complexes hake been synthesized bind characterized. Their catalytic activity has been demonstrated in Suzuki-type cross-coupling, Bind in the Heck reaction. Their redox properties have been investigated by means of cyclic voltammetry. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1425 / 1428
页数:4
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