Mechanochemical collapse of M41S mesoporous molecular sieves through hydrolysis of siloxane bonds

被引:71
作者
Tatsumi, T [1 ]
Koyano, KA [1 ]
Tanaka, Y [1 ]
Nakata, S [1 ]
机构
[1] CHIYODA CORP, KANAGAWA KU, YOKOHAMA, KANAGAWA 221, JAPAN
关键词
D O I
10.1246/cl.1997.469
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structural collapse of mesoporous molecular sieves MCM-48 and MCM-41 materials by mechanical compression was found to occur mechanochemically through the hydrolysis of Si-O-Si bonds. Their ordered structures were well retained by compressing the samples under dry N-2.
引用
收藏
页码:469 / 470
页数:2
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