Nano-electrochemical detection of hydrogen or protons using palladium nanoparticles: Distinguishing surface and bulk hydrogen

被引：41

作者：

Batchelor-McAuley, Christopher

Banks, Craig E.

Simm, Andrew O.

Jones, Timothy G. J.

Compton, Richard G.

机构：

[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

[2] Schlumberger Cambridge Res High Cross, Cambridge CB3 0EL, England

来源：

CHEMPHYSCHEM | 2006年 / 7卷 / 05期

关键词：

D O I：

10.1002/cphc.200500571

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The benefits of using nanciparticle-modified electrodes are exemplified through the electrochemical detection of protons and/or hydrogen. It is shown that a palladium-nanoporticle-modified boron-doped diamond allows voltammetric information relating to the relative roles played by the surface and the bulk metal to be obtained for the proton-hydrogen system at palladium surfaces which is not accessible using palladium macroelectrodes or microelectrodes.

引用

收藏

页码：1081 / 1085

页数：5

相关论文

共 21 条

[1] COLD FUSION - THE HEAT MECHANISM [J].

ABUTAHA, AF .

JOURNAL OF FUSION ENERGY, 1990, 9 (03) :345-349

[2] Palladium deposition on activated carbon fibre supports and electrocatalytic activity of the modified electrodes towards the hydrogen evolution reaction [J].

Andonoglou, PP ;

Jannakoudakis, AD .

ELECTROCHIMICA ACTA, 1997, 42 (12) :1905-1913

[3] A REVIEW OF THE INVESTIGATIONS OF THE FLEISCHMANN-PONS PHENOMENA [J].

BOCKRIS, JOM ;

LIN, GH ;

PACKHAM, NJC .

FUSION TECHNOLOGY, 1990, 18 (01) :11-31

[4] EFFECT OF CHEMISORBED CARBON-MONOXIDE ON THE RATE OF HYDROGEN DISSOLUTION IN PALLADIUM ELECTRODES AT POTENTIALS OF THE ALPHA-PHASE [J].

BREITER, MW .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 109 (1-3) :253-260

[5] THE EFFECT OF THE ANION ON THE TRANSFER EQUILIBRIUM AT THE (PD-H)-ELECTROLYTE INTERFACE [J].

BUCUR, RV ;

BOTA, F .

ELECTROCHIMICA ACTA, 1981, 26 (11) :1653-1655

[6] THE ELECTROCATALYTIC BEHAVIOR OF PALLADIUM IN ACID AND BASE [J].

BURKE, LD ;

CASEY, JK .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1993, 23 (06) :573-582

[7]

CHEVILLOT JP, 1975, J ELECTROANAL CHEM, V64, P39, DOI 10.1016/0368-1874(75)80110-9

[8] KINETICS OF THE ELEMENTARY STEPS OF THE HYDROGEN ELECTRODE-REACTION ON PD IN ACIDIC SOLUTION [J].

ENYO, M .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 134 (01) :75-86

[9] Preparation of 100-160-nm-sized branched palladium islands with enhanced electrocatalytic properties on HOPG [J].

Gimeno, Y ;

Creus, AH ;

González, S ;

Salverezza, RC ;

Arvia, AJ .

CHEMISTRY OF MATERIALS, 2001, 13 (05) :1857-1864

[10] High dispersion and electrocatalytic properties of palladium nanoparticles on single-walled carbon nanotubes [J].

Guo, DJ ;

Li, HL .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 286 (01) :274-279