Epoxidation and hydroxylation reactions catalyzed by the manganese and iron complexes of 5,10,15,20-tetrakis(2,6-dimethoxyphenyl)porphyrin.

被引：27

作者：

Baciocchi, E ^{[1
]}

Boschi, T ^{[1
]}

Galli, C ^{[1
]}

Lapi, A ^{[1
]}

Tagliatesta, P ^{[1
]}

机构：

[1] UNIV ROMA TOR VERGATA,DIPARTIMENTO SCI & TECNOL CHIM,I-00133 ROME,ITALY

来源：

TETRAHEDRON | 1997年 / 53卷 / 12期

关键词：

D O I：

10.1016/S0040-4020(97)00122-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Manganese(III) and iron(III) complexes of 5.10.15.20-tetrakis-(2,6-dimethoxyphenyl)porphyrin (H(2)TDMeOPP) were tested as catalysts in the epoxidation of alkenes and in the hydroxylation of adamantane with H2O2 (in the presence of imidazole) or PhIO as oxidants. The behavior of the two catalysts is compared with that of the corresponding manganese(III) and iron(III) complexes of 5,10,15,20-tetrakis-(2,6-dichlorophenyl)porphyrin and 5,10,15,20-tetraphenylporphyrin, and the observed differences ascribed to the electron donating effect of the methoxy groups. (C) 1997 Elsevier Science Ltd.

引用

页码：4497 / 4502

页数：6

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