Epoxidation of styrene by t-butyl hydroperoxide over gold supported on Yb2O3 and other rare earth oxides

被引：43

作者：

Patil, NS

Uphade, BS

Jana, P

Bhargava, SK

Choudhary, VR ^{[1
]}

机构：

[1] Natl Chem Lab, Div Chem Engn, Pune 411008, Maharashtra, India

[2] RMIT, Dept Appl Chem, Melbourne, Vic 3000, Australia

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 04期

关键词：

D O I：

10.1246/cl.2004.400

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gold nanoparticles deposited [by homogeneous deposition-precipitation (HDP) using urea] on Yb2O3 and other rare-earth oxides (viz. Sm2O3, Eu2O3, and Tb2O3) are novel highly active/selective and reusable catalysts for the selective epoxidation of styrene to styrene oxide by anhydrous or aqueous t-butyl hydroperoxide and no problems are foreseen for a large scale operation of this green process.

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页码：400 / 401

页数：2

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