Synthesis of organic-inorganic polymer hybrids having interpenetrating polymer network structure by formation of ruthenium-bipyridyl complex

被引：93

作者：

Ogoshi, T ^{[1
]}

Itoh, H ^{[1
]}

Kim, KM ^{[1
]}

Chujo, Y ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

MACROMOLECULES | 2002年 / 35卷 / 02期

关键词：

D O I：

10.1021/ma010819c

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Organic-inorganic polymer hybrids were prepared by an in-situ method. In the presence of ruthenium salt, the cross-linking reaction of bipyridyl-containing polymer was carried out together with the sol-gel reaction of tetramethoxysilane. This methodology includes the simultaneous formation of silica gel and organic gel. Using polystyrene or poly(ethylene oxide) having bipyridyl groups, organic-inorganic polymer hybrids could be prepared. The obtained polymer hybrids having IPN (interpenetrating polymer network) structure showed excellent solvent-resistant property.

引用

页码：334 / 338

页数：5

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