Photocatalytic properties of zeolite-based materials for the photoreduction of methyl orange

被引：75

作者：

Dubey, N ^{[1
]}

Rayalu, SS ^{[1
]}

Labhsetwar, NK ^{[1
]}

Naidu, RR ^{[1
]}

Chatti, RV ^{[1
]}

Devotta, S ^{[1
]}

机构：

[1] Natl Environm Engn Res Inst, Environm Mat Unit, Nagpur 440020, Maharashtra, India

来源：

APPLIED CATALYSIS A-GENERAL | 2006年 / 303卷 / 02期

关键词：

photocatalysis; zeolite; photoreduction; TiO2; transition metals; heteropolyacid;

D O I：

10.1016/j.apcata.2006.01.043

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Novel photocatalytic materials have been prepared by incorporation of TiO2, a transition metal and, heteropolyacid (HPA) in the zeolite structure. These materials have been characterized using XRD, UV-vis diffuse reflectance spectroscopy and elemental analysis. The photocatalytic activity of the materials in visible light has been evaluated for photoreduction of methyl orange solution in the presence of a sacrificial electron donor 1:40 ethanol-water mixture. The material Zeo-Y/TiO2/Co2+/HPA photoreduces, methyl orange effectively to the extent of about 4.11 mg/g TiO2 and shows better photocatalytic activity as compared to Zeo-Y/TiO2/HPA, indicating the role of transition metal ions. The improved photocatalytic properties in the visible region could be due to the combined effect of transition metal ions and HPA, while these constituents along with the zeolite framework are also likely to contribute towards delay in charge recombination. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：152 / 157

页数：6

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