Effects of various meteorological conditions and spatial emission resolutions on the ozone concentration and ROG/NOx limitation in the Milan area (I)

被引：58

作者：

Baertsch-Ritter, N ^{[1
]}

Keller, J ^{[1
]}

Dommen, J ^{[1
]}

Prevot, ASH ^{[1
]}

机构：

[1] Paul Scherrer Inst, Lab Atmospher Chem, CH-5232 Villigen, Switzerland

来源：

ATMOSPHERIC CHEMISTRY AND PHYSICS | 2004年 / 4卷

关键词：

D O I：

10.5194/acp-4-423-2004

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The three-dimensional photochemical model UAM-V is used to investigate the effects of various meteorological conditions and of the coarseness of emission inventories on the ozone concentration and ROG/NOx limitation of the ozone production in the Po Basin in the northern part of Italy. As a base case, the high ozone episode with up to 200 ppb on 13 May 1998 was modelled and previously thoroughly evaluated with measurements gained during a large field experiment. Systematic variations in meteorology are applied to mixing height, air temperature, specific humidity and wind speed. Three coarser emission inventories are obtained by resampling from 3 x 3 km(2) up to 54 x 54 km(2) emission grids. The model results show that changes in meteorological input files strongly influence ozone in this area. For instance, temperature changes peak ozone by 10.1 ppb/degreesC and the ozone concentrations in Milan by 2.8 ppb/degreesC. The net ozone formation in northern Italy is more strongly temperature than humidity dependent, while the humidity is very important for the ROG/NOx limitation of the ozone production. For all meteorological changes (e.g. doubling the mixing height), the modelled peak ozone remains ROG limited. A strong change towards NOx sensitivity in the ROG limited areas is only found if much coarser emission inventories were applied. Increasing ROG limited areas with increasing wind speed are found, because the ROG limited ozone chemistry induced by point sources is spread over a larger area. Simulations without point sources tend to increase the NOx limited areas.

引用

页码：423 / 438

页数：16

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