Iron pillared clays - Efficient catalysts for Friedel-Crafts reactions

被引：77

作者：

Choudary, BM

Kantam, ML

Sateesh, M

Rao, KK

Santhi, PL

机构：

[1] Indian Inst. of Chemical Technology, Hyderabad

来源：

APPLIED CATALYSIS A-GENERAL | 1997年 / 149卷 / 01期

关键词：

Friedel-Crafts alkylations; K10; montmorillonite; Kunipia clay; iron pillared clays; iron content; pillaring effect;

D O I：

10.1016/S0926-860X(96)00310-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Friedel-Crafts alkylations of aromatic hydrocarbons have been carried out in the presence of a series of clay catalysts originating from K10 montmorillonite and Kunipia. It was found that the iron pillared clays (FePILCs) were the most efficient catalysts producing quantitative conversions with greatly reduced amounts of catalysts in lesser reaction times. Their efficiency is attributed to the higher Fe3+ contents in the catalysts and the pillaring effect.

引用

页码：257 / 264

页数：8

共 15 条

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