The scaling behaviour of screened polyelectrolytes

被引:27
作者
Liverpool, TB
Stapper, M
机构
[1] Max-Planck-Inst. Polymerforschung, D-55021 Mainz
来源
EUROPHYSICS LETTERS | 1997年 / 40卷 / 05期
关键词
D O I
10.1209/epl/i1997-00492-x
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We present a field-theoretic renormalization group (RG) analysis of a single flexible, screened polyelectrolyte chain (a Debye-Huckel chain) in a polar solvent. We point out that the Debye-Huckel chain may be mapped onto a local field theory which has: the same fixed point as a generalised n --> 1 Potts model. Systematic analysis of the field theory shows that the system is one with two interplaying length scales requiring the calculation of scaling functions as well as exponents to fully describe its physical behaviour. To illustrate this, we solve the RG equation and explicitly calculate the exponents and the mean end-to-end length of the chain.
引用
收藏
页码:485 / 490
页数:6
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