The tridurylsilylium and tridurylstannylium cations: Free and not so free

被引：34

作者：

Lambert, JB ^{[1
]}

Lin, LJ ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 66卷 / 25期

关键词：

D O I：

10.1021/jo010772t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allyltridurylsilane has been prepared and converted to the tridurylsilylium cation by treatment with electrophiles. Allyltridurylstannane has been prepared and converted to the tridurylstannylium cation under similar conditions. The Si-29 chemical shift of the silylium cation indicates that it is free and tricoordinate, whereas the Sn-119 chemical shift of the stannylium cation indicates that it maintains loose fourth coordination with the solvent or the anion.

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页码：8537 / 8539

页数：3

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