Diastereoselectivity in the addition and cycloaddition reactions of a chiral ester of 2H-azirine-3-carboxylic acid

被引：25

作者：

Alves, MJ ^{[1
]}

Bickley, JF

Gilchrist, TL

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

[2] Univ Minho, Dept Quim, P-4710 Braga, Portugal

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1999年 / 11期

关键词：

D O I：

10.1039/a902182e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The azirine ester 2 bearing Oppolzer's N,N-diethyl-(1R)isobornyl-10-sulfonamide chiral auxiliary shows moderate diastereoselectivity in its Diels-Alder reaction with cyclopentadiene whereas the addition of thiophenol is highly diastereoselective; X-ray crystal structures of the aziridine esters 6 and 7 are reported.

引用

页码：1399 / 1401

页数：3

共 8 条

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