Structural relaxation and nanoindentation response in Zr-Cu-Ti amorphous thin films

被引:73
作者
Chou, H. S. [1 ]
Huang, J. C. [1 ]
Chang, L. W. [1 ]
Nieh, T. G. [2 ]
机构
[1] Natl Sun Yat Sen Univ, Ctr Nanosci & Nanotechnol, Dept Mat & Optoelect Sci, Kaohsiung 804, Taiwan
[2] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA
关键词
copper compounds; glass structure; hardness; indentation; metallic glasses; metallic thin films; micromechanical devices; sputtering; titanium compounds; vitrification; zirconium compounds;
D O I
10.1063/1.2999592
中图分类号
O59 [应用物理学];
学科分类号
摘要
Ternary Zr-Cu-Ti system, especial with a high Ti content, is normally difficult to be fully vitrified. In this paper, we demonstrate that cosputtering can produce amorphous Zr-Cu-Ti thin films with an excessive Ti content even as high as 19%. Sub-T-g annealing of the film induces the formation of medium-range-ordered clusters and to raise the nanohardness by 35% to 6.6 GPa. The promising mechanical properties of the sub-T-g annealed Zr52Cu29Ti19 films offer great potential for microelectromechanical system applications.
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页数:3
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