The synthesis and metal coordination chemistry of a novel phosphine- and thiolate-substituted ferrocenediyl ligand

被引：22

作者：

Gibson, VC ^{[1
]}

Long, NJ ^{[1
]}

White, AJP ^{[1
]}

Williams, CK ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 04期

关键词：

D O I：

10.1021/om010783c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel, asymmetric 1,1'-disubstituted ferrocenediyl ligand featuring phosphine and thiolate substituents has been conveniently synthesized and structurally characterized, and its coordination chemistry was probed by reaction with late transition metal reagents. Bridged dimeric species, with the thiolate S adopting a binucleating role, are observed for Pd(II) and Rh(I) metal centers, while a mononuclear, square planar Ni(II) complex is formed on reaction of the ligand with [Ni-(TMEDA)Me-2].

引用

页码：770 / 772

页数：3

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