Atmospheric pressure plasma polymerisation of metalloporphyrins containing mesoporous membranes for gas sensing applications

被引：14

作者：

Boscher, Nicolas D. ^{[1
]}

Duday, David ^{[1
]}

Heier, Philip ^{[1
,2
]}

Heinze, Katja ^{[2
]}

Hilt, Florian ^{[1
]}

Choquet, Patrick ^{[1
]}

机构：

[1] Ctr Rech Publ Gabriel Lippmann, Dept Sci & Anal Mat, L-4422 Belvaux, Luxembourg

[2] Johannes Gutenberg Univ Mainz, Inst Inorgan & Analyt Chem, D-55128 Mainz, Germany

来源：

SURFACE & COATINGS TECHNOLOGY | 2013年 / 234卷

关键词：

Plasma-polymerisation; Hexamethyldisiloxane; Mesoporous membrane; Metalloporphyrins; Colorimetric sensors; THIN-FILMS; PORPHYRIN; VAPOR; TETRAPHENYLPORPHYRIN; CAPABILITIES; DEPOSITION; RESPONSES; SENSORS; ARRAY;

D O I：

10.1016/j.surfcoat.2012.12.034

中图分类号：

TB3 [工程材料学];

学科分类号：

082905 [生物质能源与材料];

摘要：

Metalloporphyrins are embedded in an organosilicon matrix by an easily up-scalable atmospheric pressure dielectric barrier discharge method. The integrity of the metalloporphyrins, followed by UV-visible spectroscopy, is successfully preserved and their aggregation prevented. The single molecule properties, rather than the bulk ones, are thus enhanced. Exposure to triethylamine, which reaches the metalloporphyrins through the pores of the organosilicon membrane, led to a shift in the absorption spectrum and confirms the gas sensing potential of such coatings. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：48 / 52

页数：5

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