Phthalocyanines-MWCNT hybrid materials: Fabrication, aggregation and photoconductivity properties improvement

被引:38
作者
Yang, Zhenglong [1 ]
Pu, Hongting [1 ]
Yuan, Junjie [1 ]
Wan, Decheng [1 ]
Liu, Yongsheng [2 ]
机构
[1] Tongji Univ, Inst Funct Polymer Mat, Key Lab Adv Civil Engn Mat, Inst Adv Mat & Nano Biomed,Coll Mat Sci & Engn, Shanghai 200092, Peoples R China
[2] Shanghai Univ Elect Power, Dept Math & Phys, Inst Solar Energy, Shanghai 200090, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/j.cplett.2008.09.043
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The 2,9,16-trilauryloxy-23-hexyloxy substituted copper phthalocyanines multiwall carbon nanotubes (CuPc(OC12H25)3(OC6H13)-MWCNT) hybrid materials were facilely prepared by a chemical functionalization method. The aggregation structures of resulting hybrid materials have been characterized by TEM, SEM, FTIR, XRD and UV-vis measurements. The CuPc(OC12H25)(3)(OC6H13)-MWCNT hybrid materials exhibit good solution storage stability and a low aggregation tendency due to the chemical bonding between MWCNT and asymmetrically substituted phthalocyanines. The enhancement of the photoconductivity of phthalocyanines-MWCNT hybrid materials has been investigated in terms of interaction effects of phthalocyanines and MWCNT. It could supply a new way to fabricate a light energy conversion materials. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:73 / 77
页数:5
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