meso-Pyridyl BODIPYs with tunable chemical, optical and electrochemical properties

被引：43

作者：

Bartelmess, Juergen ^{[1
]}

Weare, Walter W. ^{[1
]}

Latortue, Narah ^{[2
]}

Duong, Christina ^{[2
]}

Jones, Daniel S. ^{[2
]}

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

[2] Univ N Carolina, Dept Chem, Charlotte, NC 28223 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2013年 / 37卷 / 09期

关键词：

ELECTROGENERATED CHEMILUMINESCENCE; ELECTRON-TRANSFER; SPECTROSCOPIC PROPERTIES; HIGHLY FLUORESCENT; ENERGY-TRANSFER; DYES; COMPLEXES; DERIVATIVES; PORPHYRIN; BORADIAZAINDACENE;

D O I：

10.1039/c3nj00426k

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

A series of meso-pyridyl substituted BODIPY molecules has been synthesized, characterized and their optical and electrochemical properties compared. By utilizing ethanol and dichloromethane during the initial condensation reactions, there is a significant increase in the isolated yields compared to standard protocols. The properties of the highly fluorescent BODIPYs could be tuned by modifying the substituents of the pyridine, leading to pyridyl BODIPY as prospective ligands for future metal complexes. Furthermore, the presented BODIPY derivatives are shown to be applicable for fluorescence pH sensing over selective pH ranges.

引用

页码：2663 / 2668

页数：6

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