Voltammetry in solutions of low ionic strength. Electrochemical and analytical aspects

被引：105

作者：

Ciszkowska, M

Stojek, Z

机构：

[1] CUNY Brooklyn Coll, Dept Chem, Brooklyn, NY 11210 USA

[2] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1999年 / 466卷 / 02期

关键词：

voltammetry; migration; microelectrodes; low support ratio; absence of supporting electrolyte;

D O I：

10.1016/S0022-0728(99)00141-2

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Recent progress in microelectrode voltammetry in solutions without or with low concentrations of supporting electrolyte is reviewed. The following points are addressed: mathematical treatment of transport, experimental setup, steady state and non steady state transport, migration coupled with homogeneous equilibrium, voltammetry in undiluted redox liquids, studies on the mechanism of the electrode processes, transport of ions in solutions of polyelectrolytes and colloids, and analytical applications. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：129 / 143

页数：15

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