Design and synthesis of 3d-4f metal-based zeolite-type materials with a 3D nanotubular structure encapsulated "water" pipe

被引：623

作者：

Zhao, B ^{[1
]}

Cheng, P ^{[1
]}

Chen, XY ^{[1
]}

Cheng, C ^{[1
]}

Shi, W ^{[1
]}

Liao, DZ ^{[1
]}

Yan, SP ^{[1
]}

Jiang, ZH ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 10期

关键词：

D O I：

10.1021/ja038784e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nanotubular 3D heterometallic zeolitic polymer, {[Yb(PDA)3Mn1.5(H2O)3]·1.5H2O}n (2), was designed and synthesized by simply tuning the amount of coordinated water on the Mn ion in the molecular ladder polymer {[Yb(PDA)3Mn1.5(H2O)6]·6H2O}n (1). 1 and 2 were structurally and magnetically characterized. The water molecules capsulated within the nanotube were arrayed into an unprecedented water" pipe. The robust 2 retained intact networks after the removal of guest water trapped in the nanotubes and even after methanol replaced guest water. Copyright © 2004 American Chemical Society."

引用

页码：3012 / 3013

页数：2

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