Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes

被引：69

作者：

Aime, S

Barge, A

Batsanov, AS

Botta, M

Delli Castelli, D

Fedeli, F

Mortillaro, A

Parker, D

Puschmann, H

机构：

[1] Univ Turin, Dipartimento Chim IFM, I-10125 Turin, Italy

[2] Lab Integrato Metodol Avanzate, I-10010 Colleretto Giacosa, TO, Italy

[3] Univ Piemonte Orientale Amedeo Avogadro, Dipartimento Sci & Tecnol Avanzate, I-15100 Alessandria, Italy

[4] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 10期

关键词：

D O I：

10.1039/b202862j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.

引用

页码：1120 / 1121

页数：2

共 12 条

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