Dependency of Aluminum Collector Corrosion in Lithium Ion Batteries on the Electrolyte Solvent

被引：119

作者：

Kraemer, Elisabeth ^{[1
]}

Passerini, Stefano ^{[1
]}

Winter, Martin ^{[1
]}

机构：

[1] Univ Munster, Inst Phys Chem, MEET Battery Res Ctr, D-48149 Munster, Germany

来源：

ECS ELECTROCHEMISTRY LETTERS | 2012年 / 1卷 / 05期

关键词：

CARBONATE-BASED ELECTROLYTES; NONAQUEOUS ELECTROLYTES; CYCLING BEHAVIORS; SELF-DISCHARGE; SALTS; ADDITIVES; CELLS;

D O I：

10.1149/2.004205eel

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The corrosion behavior of aluminum current collectors at high potentials in the presence of the electrolyte salt LiN(SO2CF3)(2) and various electrolyte solvents is studied. The corrosion is investigated, by detection of the actual weight loss of the current collector. Collector corrosion depends on the chemistry of the electrolyte solvent, with strong corrosion in the presence of carbonates and lactones and minimal corrosion in the presence of nitriles. It is demonstrated that not only a charge consuming aluminum dissolution takes place and possible explanations are discussed. (C) 2012 The Electrochemical Society. All rights reserved.

引用

页码：C9 / C11

页数：3

共 36 条

[1] Stability of aluminum substrates in lithium-ion battery electrolytes [J].

Behl, WK ;

Plichta, EJ .

JOURNAL OF POWER SOURCES, 1998, 72 (02) :132-135

[2]

Besenhard JO, 2002, CHEMPHYSCHEM, V3, P155, DOI 10.1002/1439-7641(20020215)3:2<155::AID-CPHC155>3.0.CO

[3]

2-S

[4] Insertion reactions in advanced electrochemical energy storage [J].

Besenhard, JO ;

Winter, M .

PURE AND APPLIED CHEMISTRY, 1998, 70 (03) :603-608

[5] INORGANIC FILM-FORMING ELECTROLYTE ADDITIVES IMPROVING THE CYCLING BEHAVIOR OF METALLIC LITHIUM ELECTRODES AND THE SELF-DISCHARGE OF CARBON LITHIUM ELECTRODES [J].

BESENHARD, JO ;

WAGNER, MW ;

WINTER, M ;

JANNAKOUDAKIS, AD ;

JANNAKOUDAKIS, PD ;

THEODORIDOU, E .

JOURNAL OF POWER SOURCES, 1993, 44 (1-3) :413-420

[6] Corrosion of lithiuim-ion battery current collectors [J].

Braithwaite, JW ;

Gonzales, A ;

Nagasubramanian, G ;

Lucero, SJ ;

Peebles, DE ;

Ohlhausen, JA ;

Cieslak, WR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (02) :448-456

[7] THERMALLY STABLE LITHIUM-SALTS FOR POLYMER ELECTROLYTES [J].

DOMINEY, LA ;

KOCH, VR ;

BLAKLEY, TJ .

ELECTROCHIMICA ACTA, 1992, 37 (09) :1551-1554

[8] Lithium bis(fluorosulfonyl)imide (LiFSI) as conducting salt for nonaqueous liquid electrolytes for lithium-ion batteries: Physicochemical and electrochemical properties [J].

Han, Hong-Bo ;

Zhou, Si-Si ;

Zhang, Dai-Jun ;

Feng, Shao-Wei ;

Li, Li-Fei ;

Liu, Kai ;

Feng, Wen-Fang ;

Nie, Jin ;

Li, Hong ;

Huang, Xue-Jie ;

Armand, Michel ;

Zhou, Zhi-Bin .

JOURNAL OF POWER SOURCES, 2011, 196 (07) :3623-3632

[9] SELECTIVE CYCLOALKANONE REDUCTIONS USING ALUMINUM AMALGAM [J].

HULCE, M ;

LAVAUTE, T .

TETRAHEDRON LETTERS, 1988, 29 (05) :525-528

[10] High flash point electrolyte for use in lithium-ion batteries [J].

Isken, P. ;

Dippel, C. ;

Schmitz, R. ;

Schmitz, R. W. ;

Kunze, M. ;

Passerini, S. ;

Winter, M. ;

Lex-Balducci, A. .

ELECTROCHIMICA ACTA, 2011, 56 (22) :7530-7535

← 1 2 3 4 →