Sulfide accumulation and sensing based on electrochemical processes in microdroplets of N1-[4-(dihexylamino)phenyl]-N1,N4,N4-trihexyl-1,4-phenylenediamine

被引：29

作者：

Marken, F

Blythe, A

Compton, RG

Bull, SD

Davies, SG

机构：

[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

[2] Univ Oxford, Dyson Perrins Lab, Oxford OX1 3QY, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a905278j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electroanalytical sulfide detection via oxidation of N-1-[4-(dihexylamino)phenyl]-N-1,N-4,N-4-trihexyl-1,4-phenylene diamine (DPTPD) deposited in form of microdroplets onto basal plane pyrolytic graphite electrodes immersed in aqueous 0.1 M NaClO4 containing sulfide is proposed to be associated with two consecutive reversible one electron processes accompanied by ClO4- uptake, sulfide accumulation, and formation of a methylene blue derivative.

引用

页码：1823 / 1824

页数：2

共 8 条

[1]

BARD AJ, 1980, ELECTROCHEMICAL METH, P523

[2] POLYMER-COATED ELECTRODES - CYCLIC VOLTAMMETRY AND CHRONOAMPEROMETRY OF NON-IDEAL SYSTEMS - THE ANODIC-OXIDATION OF POLY(4-VINYL-TRIPHENYLAMINE) FILMS [J].