Interplay between time-temperature transformation and the liquid-liquid phase transition in water

被引：222

作者：

Yamada, M ^{[1
]}

Mossa, S

Stanley, HE

Sciortino, F

机构：

[1] Boston Univ, Ctr Polymer Studies, Boston, MA 02215 USA

[2] Boston Univ, Dept Phys, Boston, MA 02215 USA

[3] Univ Roma La Sapienza, Dipartimento Fis, INFM, UdR, I-00185 Rome, Italy

[4] Univ Roma La Sapienza, INFM, Ctr Stat Mech & Complex, I-00185 Rome, Italy

来源：

PHYSICAL REVIEW LETTERS | 2002年 / 88卷 / 19期

关键词：

D O I：

10.1103/PhysRevLett.88.195701

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We study the new water model proposed by Mahoney and Jorgensen [J. Chem. Phys. 112, 8910 (2000)], which is closer to real water than previously proposed classical pairwise additive potentials. We simulate the model in a wide range of deeply supercooled states and find (i) the existence of a nonmonotonic "nose-shaped" temperature of maximum density line and a nonreentrant spinodal, (ii) the presence of a low-temperature phase transition, (iii) the free evolution of bulk water to ice, and (iv) the time-temperature-transformation curves at different densities.

引用

页数：4

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