Conjugated polyrotaxanes containing coordinating units

被引：9

作者：

Vidal, PL

Divisia-Blohorn, B

Billon, M

Bidan, G

Kern, JM

Sauvage, JP

机构：

[1] CEA Grenoble, DRFMC, EMSI, UMR 5819, F-38054 Grenoble 9, France

[2] Univ Strasbourg, Inst Le Bel, UMR 7513, Lab Chim Organominerale, F-67070 Strasbourg, France

来源：

SYNTHETIC METALS | 1999年 / 102卷 / 1-3期

关键词：

electrochemical polymerization; X-ray absorption spectroscopy; special-purpose functionalized conjugated polymers;

D O I：

10.1016/S0379-6779(98)00556-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A polyrotaxane containing a conjugated backbone has been synthesized via;a copper(I) template and electropolymerisation The reversibility of Cu(I) binding is perfect only when lithium is present during copper removal, acting as labile scaffolding. The ability of our structure for other transition metal ion sensing has also been tested Potential shifts seem to indicate interactions between redox active copper centers and the conjugated backbone are under study.

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收藏

页码：1478 / 1479

页数：2

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