Kinetics of dispersion polymerization of styrene in ethanol .1. Model development

被引：33

作者：

Ahmed, SF

Poehlein, GW

机构：

[1] School of Chemical Engineering, Georgia Institute of Technology, Atlanta

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1997年 / 36卷 / 07期

关键词：

D O I：

10.1021/ie960505r

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Dispersion polymerization in polar organic media is a heterogeneous polymerization process that combines solution polymerization in the continuous phase with microbulk polymerization in the disperse particle phase. The relative prevalence of the two polymerization modes is dependent on a number of reaction variables. A mechanistic picture of dispersion polymerization during the particle growth phase is presented and mathematical models of the rate of polymerization and particle growth during seeded batch and continuous polymerization is developed.

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页码：2597 / 2604

页数：8

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