Synthesis, growth and characterization of 2-carboxypyridinium hydrogen (2R,3R)-tartrate monohydrate: A new organic nonlinear optical crystal

被引：6

作者：

Gowri, S. ^{[1
]}

Devi, T. Uma ^{[2
]}

Sajan, D. ^{[3
]}

Chandramohan, A. ^{[4
]}

Lawrence, N. ^{[5
]}

机构：

[1] Cauvery Coll Women, Dept Phys, Tiruchirappalli 620018, Tamil Nadu, India

[2] Govt Arts Coll Women Autonomous, Dept Phys, Pudukkottai, India

[3] Bishop Moore Coll, Dept Phys, Alappuzha 690110, Kerala, India

[4] SRMV Coll Arts & Sci, Dept Chem, Coimbatore 641020, Tamil Nadu, India

[5] St Josephs Coll Autonomous, Dept Phys, Tiruchirappalli 620018, Tamil Nadu, India

来源：

OPTIK | 2013年 / 124卷 / 16期

关键词：

X-ray diffraction; Recrystallization; Growth from solutions; Nonlinear optic materials; SINGLE-CRYSTAL;

D O I：

10.1016/j.ijleo.2012.07.049

中图分类号：

O43 [光学];

学科分类号：

070207 [光学];

摘要：

Single crystals of 2-carboxypyridinium hydrogen (2R,3R)-tartrate monohydrate, an organic nonlinear optical material has been grown by slow solvent evaporation technique. The single crystal X-ray diffraction (XRD) data revealed the noncentrosymmetric crystal structure, which is an essential criterion for second harmonic generation. The crystalline nature of the grown crystals was confirmed using powder XRD technique. The functional group of the compound is identified by FTIR spectrum. The thermal stability has been identified for the new title compound. The UV-vis spectrum shows the lower optical cut off at 300 nm and transparent in the visible region. The second harmonic generation efficiency was found using Kurtz powder technique. The mechanical properties of the grown crystals have been studied using Vickers microhardness tester. (C) 2012 Elsevier GmbH. All rights reserved.

引用

页码：2393 / 2396

页数：4

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