A novel UV-mediated low-temperature sintering of TiO2 for dye-sensitized solar cells

被引:52
作者
Lewis, LN [1 ]
Spivack, JL [1 ]
Gasaway, S [1 ]
Williams, ED [1 ]
Gui, JY [1 ]
Manivannan, V [1 ]
Siclovan, OP [1 ]
机构
[1] GE Global Res, Niskayuna, NY 12309 USA
关键词
titania; solar cells; dye-sensitized solar cells;
D O I
10.1016/j.solmat.2005.05.019
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Titania pastes were fired at 450 degrees C in oxygen to give white titania that was used to prepare dye-sensitized solar cells (DSSC). Titania fired at lower temperature and/or under inert atmosphere have brown stripes and cells made from these stripes had no measurable efficiency. When the titania paste was screen printed and then heated and simultaneously irradiated with UV light, white stripes were obtained. improved efficiency was noted for PV cells made from pastes heated at lower temperature under irradiation vs. cells made from low-temperature heated paste but without irradiation. UV irradiation appears to facilitate clean oxidation of residual organic materials in the titania precursor pastes. The best cells in our study made with our titania paste treated at 450 degrees C in oxygen had the following characteristics: efficiency = 3.45 %; V-oc = 630 mV; J(sc) = 8.5 mA/cm(2); and a fill factor = 0.64. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1041 / 1051
页数:11
相关论文
共 8 条
[1]   Photoelectrochemical cells [J].
Grätzel, M .
NATURE, 2001, 414 (6861) :338-344
[2]   Molecular photovoltaics [J].
Hagfeldt, A ;
Grätzel, M .
ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (05) :269-277
[3]   TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations - A review [J].
Konstantinou, IK ;
Albanis, TA .
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2004, 49 (01) :1-14
[4]  
MUSZKAT L, 1998, PESTICIDE REMEDIATIO, P307
[5]   Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells [J].
Nazeeruddin, MK ;
Péchy, P ;
Renouard, T ;
Zakeeruddin, SM ;
Humphry-Baker, R ;
Comte, P ;
Liska, P ;
Cevey, L ;
Costa, E ;
Shklover, V ;
Spiccia, L ;
Deacon, GB ;
Bignozzi, CA ;
Grätzel, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (08) :1613-1624
[6]   MECHANISM OF THE PHOTOOXIDATIVE DEGRADATION OF ORGANIC POLLUTANTS OVER TIO2 PARTICLES [J].
PELIZZETTI, E ;
MINERO, C .
ELECTROCHIMICA ACTA, 1993, 38 (01) :47-55
[7]  
SAHLEDEMESSIE E, 2000, ACS SYM SER, V767, P217
[8]   Synthesis of TiO2 nanocrystals by nonhydrolytic solution-based reactions [J].
Trentler, TJ ;
Denler, TE ;
Bertone, JF ;
Agrawal, A ;
Colvin, VL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (07) :1613-1614