Magnetic characterization of the sawtooth-lattice olivines ZnL2S4 (L=Er,Tm,Yb) -: art. no. 012413

被引:26
作者
Lau, GC [1 ]
Ueland, BG
Freitas, RS
Dahlberg, ML
Schiffer, P
Cava, RJ
机构
[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
[2] Penn State Univ, Dept Phys, University Pk, PA 16802 USA
[3] Penn State Univ, Mat Res Inst, University Pk, PA 16802 USA
来源
PHYSICAL REVIEW B | 2006年 / 73卷 / 01期
关键词
D O I
10.1103/PhysRevB.73.012413
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report the magnetic properties of the ZnL2S4 (L=Er,Tm,Yb) olivines, in which the magnetic lanthanide ions are in a potentially frustrated geometry consisting of sawtooth chains of corner-sharing triangles. Fits to the high-temperature magnetic susceptibility yielded Curie-Weiss temperatures of theta(W)approximate to-4, -13, and -75 K for the Er, Tm, and Yb compounds, respectively. None of the compounds displayed magnetic long-range order above T=1.8 K. The lack of ordering at temperatures near theta(W) may be attributed to either the low dimensionality of the structure or the frustrating effect of the triangular geometry.
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