Scope of the Suzuki-Miyaura Cross-Coupling Reaction of Potassium Trifluoroboratoketohomoenolates

被引：40

作者：

Molander, Gary A. ^{[1
]}

Jean-Gerard, Ludivine ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 03期

基金：

美国国家卫生研究院;

关键词：

CATALYZED BETA-BORATION; ZINC HOMOENOLATE; ALPHA; BETA-UNSATURATED KETONES; CARBONYL-COMPOUNDS; ARYL CHLORIDES; ESTERS; CHEMISTRY; ACYLATION; BIS(PINACOLATO)DIBORON; SILOXYCYCLOPROPANES;

D O I：

10.1021/jo802453m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Potassium trifluoroboratoketohomoenolates were prepared in good yields from either the corresponding alpha,beta-unsaturated compounds or methyl ketones. These organoboron reagents were effectively cross-coupled with various aryl and heteroaryl chlorides.

引用

页码：1297 / 1303

页数：7

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