Overcoming the shortcomings of the Nernst-Planck model

被引：83

作者：

Dreyer, Wolfgang ^{[1
]}

Guhlke, Clemens ^{[1
]}

Mueller, Ruediger ^{[1
]}

机构：

[1] Weierstrass Inst, D-10117 Berlin, Germany

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2013年 / 15卷 / 19期

关键词：

MIXTURES;

D O I：

10.1039/c3cp44390f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This is a study on electrolytes that takes a thermodynamically consistent coupling between mechanics and diffusion into account. It removes some inherent deficiencies of the popular Nernst-Planck model. A boundary problem for equilibrium processes is used to illustrate the features of the new model.

引用

收藏

页码：7075 / 7086

页数：12

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