The tuning of binding properties via the change in cavity size of unsaturated palladium trinuclear clusters

被引：18

作者：

Zhang, TL

Drouin, M

Harvey, PD

机构：

[1] UNIV SHERBROOKE,DEPT CHIM,SHERBROOKE,PQ J1K 2R1,CANADA

[2] UNIV SHERBROOKE,LAB DIFFRACT RAYONS X,SHERBROOKE,PQ J1K 2R1,CANADA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 07期

关键词：

D O I：

10.1039/cc9960000877

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An increase in cavity size is achieved by using dpam instead of dppm (As instead of P) in the [Pd-3(dpam)(3)(CO)](2+) cluster host, which results in an increase in binding constants with various neutral and anionic substrates.

引用

页码：877 / 878

页数：2

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