A role for free phosphinidenes in the reaction of magnesium and sterically encumbered ArPCl2 in solution at room temperature

被引：39

作者：

Smith, RC ^{[1
]}

Shah, S ^{[1
]}

Protasiewicz, JD ^{[1
]}

机构：

[1] Case Western Reserve Univ, Dept Chem, Cleveland, OH 44106 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 646卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

phosphorus; phosphinidene; cyclometallation; diphosphene; magnesium; meta-terphenyl;

D O I：

10.1016/S0022-328X(01)01384-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction of ArPCl2 (Ar = 2,6-Trip(2)C(6)H(3), 2,6-Mes(2)C(6)H(3), 2,6-(2,6-Me2C6H3)(2)C6H3, or 2,4,6-(Bu3C6H3)-Bu-t) by various forms of activated magnesium have been examined and compared with previously reported reductions using unactivated magnesium. The current reactions are more rapid and give rise to products that are reminiscent of products obtained by irradiation of phosphanylidene-sigma(4)-phosphoranes ArP-PMe3 bearing the same Ar groups. The correlation in product distributions suggests the involvement of phosphinidenes in the reduction of aryldichlorophosphines by activated magnesium. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：255 / 261

页数：7

共 23 条

[1] Flash vacuum pyrolysis of dichlorophosphines over magnesium: Generation and reactivity of simple phosphinidenes [J].

Aitken, RA ;

Masamba, W ;

Wilson, NJ .

TETRAHEDRON LETTERS, 1997, 38 (48) :8417-8420

[2] ACTIVATED METALS - PROCEDURE FOR PREPARATION OF ACTIVATED MAGNESIUM AND ZINC [J].

ARNOLD, RT ;

KULENOVIC, ST .

SYNTHETIC COMMUNICATIONS, 1977, 7 (03) :223-232

[3] CHEMISTRY OF PHOSPHORUS .218. MONOCYCLIC AND POLYCYCLIC PHOSPHANES [J].

BAUDLER, M ;

GLINKA, K .

CHEMICAL REVIEWS, 1993, 93 (04) :1623-1667

[4] EVIDENCE FOR SURFACE PHOSPHINIDENE INTERMEDIATES [RP-]MG] IN THE HETEROGENEOUS DECHLORINATION OF ALKYLDICHLOROPHOSPHANES RPCL2 BY MG METAL [J].

BOCK, H ;

BANKMANN, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (16) :1130-1132

[5] THE PREPARATION OF FINELY DIVIDED METAL POWDERS AND TRANSITION-METAL COMPLEXES USING ORGANICALLY SOLVATED MAGNESIUM [J].

BONNEMANN, H ;

BOGDANOVIC, B ;

BRINKMANN, R ;

SPLIETHOFF, B ;

HE, DW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 451 (1-2) :23-31

[6] HIGHLY REACTIVE MAGNESIUM AND ITS APPLICATION TO ORGANIC SYNTHESES [J].

BURNS, TP ;

RIEKE, RD .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (16) :3674-3680

[7] LASER IRRADIATION OF A DIPHOSPHENE - EVIDENCE FOR THE 1ST CIS-TRANS ISOMERIZATION [J].

CAMINADE, AM ;

VERRIER, M ;

ADES, C ;

PAILLOUS, N ;

KOENIG, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (13) :875-877

[8] SYNTHESIS AND CHARACTERIZATION OF 2,4,6-TRI-TERT-BUTYLPHENYLPHOSPHINES - X-RAY STRUCTURE OF [P(C6H2BUT3-2,4,6)S]3 [J].

CETINKAYA, B ;

HITCHCOCK, PB ;

LAPPERT, MF ;

THORNE, AJ ;

GOLDWHITE, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (12) :691-693

[9] DIPHOSPHENES (RP=PR) - SYNTHESIS AND NMR CHARACTERIZATION [J].

COWLEY, AH ;

KILDUFF, JE ;

NEWMAN, TH ;

PAKULSKI, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (21) :5820-5821

[10] NEW APPROACHES TO THE GENERATION OF PHOSPHINIDENES [J].

COWLEY, AH ;

GABBAI, F ;

SCHLUTER, R ;

ATWOOD, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (08) :3142-3144

← 1 2 3 →