The methoxymethyl cation cleaves peptide bonds in the gas phase

被引：20

作者：

Freitas, MA

OHair, RAJ

Dua, S

Bowie, JH

机构：

[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA

[2] UNIV ADELAIDE,DEPT CHEM,ADELAIDE,SA 5005,AUSTRALIA

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 15期

关键词：

D O I：

10.1039/a703335d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methoxymethyl cations and simple N-acyl amino acids and dipeptides react in the gas phase to form [M + MeOCH2](+) ions which fragment via a number of pathways including amide bond cleavage.

引用

页码：1409 / 1410

页数：2

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