Catalytic asymmetric cyclopropanation of electron deficient alkenes mediated by chiral sulfides

被引：49

作者：

Aggarwal, VK ^{[1
]}

Smith, HW ^{[1
]}

Jones, RVH ^{[1
]}

Fieldhouse, R ^{[1
]}

机构：

[1] ZENECA PROC TECHNOL DEPT,GRANGEMOUTH,STIRLING,SCOTLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a704214k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic asymmetric cylopropanation of enones has been achieved using diazo compounds, catalytic quantities of a metal catalyst and a camphor-derived thioacetal; this sulfide shows exceptionally high levels of enantioselectivity.

引用

页码：1785 / 1786

页数：2

共 23 条

[1] A novel catalytic cycle for the synthesis of epoxides using sulfur ylides
Aggarwal, VK
AbdelRahman, H
Fan, L
Jones, RVH
Standen, MCH
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (08) : 1024 - 1030
[2] Direct asymmetric epoxidation of aldehydes using catalytic amounts of enatiomerically pure sulfides
Aggarwal, VK
Ford, JG
Thompson, A
Jones, RVH
Standen, MCH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (29) : 7004 - 7005
[3] Novel catalytic and asymmetric process for aziridination mediated by sulfur ylides
Aggarwal, VK
Thompson, A
Jones, RVH
Standen, MCH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (24) : 8368 - 8369
[4] PHOTOLYSIS OF PHENYLDIAZOMETHANES AND DIPHENYLDIAZOMETHANES IN ALKYL AND ALLYLIC SULFIDES
ANDO, W
YAMADA, M
MIGITA, T
MATSUZAK.E
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (24) : 3791 - &
[5] [Anonymous], COMPREHENSIVE ORGANI
[6] Block E., 1981, CHEM SULPHONIUM GR 2, P673
[7] IMPROVED PROCEDURE FOR THE SYNTHESIS OF ENANTIOMERICALLY ENRICHED CYCLOPROPYLMETHANOL DERIVATIVES
CHARETTE, AB
PRESCOTT, S
BROCHU, C
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (04) : 1081 - 1083
[8] DESIGN OF AMPHOTERIC BIFUNCTIONAL LIGANDS - APPLICATION TO THE ENANTIOSELECTIVE SIMMONS-SMITH CYCLOPROPANATION OF ALLYLIC ALCOHOLS
CHARETTE, AB
JUTEAU, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (06) : 2651 - 2652
[9] ALPHA-HYDROXY ESTERS AS CHIRAL AUXILIARIES IN ASYMMETRIC CYCLOPROPANATIONS BY RHODIUM(II)-STABILIZED VINYLCARBENOIDS
DAVIES, HML
HUBY, NJS
CANTRELL, WR
OLIVE, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) : 9468 - 9479
[10] BIS(OXAZOLINES) AS CHIRAL LIGANDS IN METAL-CATALYZED ASYMMETRIC REACTIONS - CATALYTIC, ASYMMETRIC CYCLOPROPANATION OF OLEFINS
EVANS, DA
WOERPEL, KA
HINMAN, MM
FAUL, MM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (02) : 726 - 728

← 1 2 3 →