Delamination of surfactant intercalated smectites in alcohols: Effect of chain length of the solvent

被引:27
作者
Venugopal, BR
Sen, S
Shivakumara, C
Rajamathi, M
机构
[1] St Josephs Coll, Dept Chem, Bangalore 560027, Karnataka, India
[2] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
关键词
smectites; organoclays; intercalation; delamination;
D O I
10.1016/j.clay.2005.11.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cetyl trimethylammonium and stearyl trimethylammonium ion-intercalated montmorillonite delaminates in alcohols. While delamination is observed in all alcohols, the amount of delaminated particles and the stability of the resultant colloidal dispersion increases with the chain length of the alcohol. The organoclay could be easily reassembled from the colloidal dispersions either by evaporation or by the addition of a polar solvent. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:141 / 146
页数:6
相关论文
共 28 条
[1]   Delamination of layered double hydroxides by use of surfactants [J].
Adachi-Pagano, M ;
Forano, C ;
Besse, JP .
CHEMICAL COMMUNICATIONS, 2000, (01) :91-92
[2]   Monolayer to bilayer transitional arrangements of hexadecyltrimethylammonium cations on Na-montmorillonite [J].
Bonczek, JL ;
Harris, WG ;
Nkedi-Kizza, P .
CLAYS AND CLAY MINERALS, 2002, 50 (01) :11-17
[3]   Thermoset-layered silicate nanocomposites. quaternary ammonium montmorillonite with primary diamine cured epoxies [J].
Brown, JM ;
Curliss, D ;
Vaia, RA .
CHEMISTRY OF MATERIALS, 2000, 12 (11) :3376-3384
[4]   Synthetic organo- and polymer-clays: preparation, characterization, and materials applications [J].
Carrado, KA .
APPLIED CLAY SCIENCE, 2000, 17 (1-2) :1-23
[5]   INTERACTIONS OF HYDROPHOBIC LAYER SILICATES WITH ALCOHOL-BENZENE MIXTURES .1. ADSORPTION-ISOTHERMS [J].
DEKANY, I ;
SZANTO, F ;
WEISS, A ;
LAGALY, G .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1986, 90 (05) :422-427
[6]   INTERACTIONS OF HYDROPHOBIC LAYER SILICATES WITH ALCOHOL-BENZENE MIXTURES .2. STRUCTURE AND COMPOSITION OF THE ADSORPTION LAYER [J].
DEKANY, I ;
SZANTO, F ;
WEISS, A ;
LAGALY, G .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1986, 90 (05) :427-431
[7]   Catalytic synthesis of carbon nanotubes on clay minerals [J].
Gournis, D ;
Karakassides, MA ;
Bakas, T ;
Boukos, N ;
Petridis, D .
CARBON, 2002, 40 (14) :2641-2646
[8]   New approach to the delamination of layered double hydroxides [J].
Hibino, T ;
Jones, W .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (05) :1321-1323
[9]   Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD [J].
Jobbagy, M ;
Regazzoni, AE .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 275 (01) :345-348
[10]  
JOHNS WD, 1967, AM MINERAL, V52, P1706