Oxidative decarboxylation of α-amino acids:: A mild and efficient method for the generation of N-acyliminium ions

被引：45

作者：

Boto, A ^{[1
]}

Hernández, R ^{[1
]}

Suárez, E ^{[1
]}

机构：

[1] CSIC, Inst Prod Nat & Agrobiol, San Cristobal la Laguna 38206, Tenerife, Spain

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 32期

关键词：

D O I：

10.1016/S0040-4039(99)01180-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidative decarboxylation of cr-amino acids using the system (diacetoxyiodo)benzene or iodosylbenzene and iodine proceeded smoothly at room temperature. The intermediacy of an N-acyliminium cation has been demonstrated through intermolecular and intramolecular trapping with nucleophiles. (C) 1999 Published by Elsevier Science Ltd. An rights reserved.

引用

页码：5945 / 5948

页数：4

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