Orientations of the lamellar phase of block copolymer melts under oscillatory shear flow

被引:25
作者
Morozov, AN
Fraaije, JGEM
机构
[1] Leiden Univ, Inst Lorentz Theoret Phys, NL-2300 RA Leiden, Netherlands
[2] Leiden Univ, Leiden Inst Chem, Soft Condensed Matter Grp, NL-2300 RA Leiden, Netherlands
来源
PHYSICAL REVIEW E | 2002年 / 65卷 / 03期
关键词
D O I
10.1103/PhysRevE.65.031803
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We develop a theory to describe the reorientation phenomena in the lamellar phase of block copolymer melts under reciprocating shear flow. We show that, similar to the steady shear, the oscillating flow anisotropically suppresses fluctuations and gives rise to the parallel to-->perpendicular to transition. The experimentally observed high-frequency reverse transition is explained in terms of interaction between the melt and the shear-cell walls.
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页数:3
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