High electronic conductivity molybdenum disulfide-dialkylamino nanocomposites

被引:51
作者
Sánchez, V
Benavente, E
Ana, MAS
González, G
机构
[1] Univ Chile, Fac Sci, Dept Chem, Santiago, Chile
[2] Univ Tecnol Metropolitana, Dept Chem, Santiago, Chile
关键词
D O I
10.1021/cm9900711
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reaction of alkylamines with exfoliated MoS2 leads to the novel series of organic-inorganic nacomposites Li0.1MoS2(HNR2)(y) in which the amine is densely intercalated in the disulfide interlaminar spaces. The products are mixed ionic-electronic conductors with electrical conductivities at room temperature as high as 10(-1) S cm(-1).
引用
收藏
页码:2296 / +
页数:4
相关论文
共 25 条
[1]   Calorimetric study of intercalation of n-alkyldiamines into alpha-titanium hydrogenphosphate [J].
Airoldi, C ;
Roca, S .
JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (12) :1963-1966
[2]   Ionic transport properties of mixed conductors: Application of AC and DC methods to silver telluride [J].
Andreaus, R ;
Sitte, W .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (03) :1040-1044
[3]   Toward pillared layered metal sulfides. Intercalation of the chalcogenide clusters Co(6)Q(8)(PR(3))(6) (Q=S, Se, and Te and R=alkyl) into MoS2 [J].
Bissessur, R ;
Heising, J ;
Hirpo, W ;
Kanatzidis, M .
CHEMISTRY OF MATERIALS, 1996, 8 (02) :318-&
[4]   IRON-INTERCALATED MOLYBDENUM-DISULFIDE OBTAINED FROM SINGLE-LAYER DISPERSION [J].
DANOT, M ;
MANSOT, JL ;
GOLUB, AS ;
PROTZENKO, GA ;
FABRITCHNYI, PB ;
NOVIKOV, YN ;
ROUXEL, J .
MATERIALS RESEARCH BULLETIN, 1994, 29 (08) :833-841
[5]   INTERCALATION OF METALLOCENES IN LAYERED TRANSITION-METAL DICHALCOGENIDES [J].
DINES, MB .
SCIENCE, 1975, 188 (4194) :1210-1211
[6]   INCLUSION SYSTEMS OF ORGANIC-MOLECULES IN RESTACKED SINGLE-LAYER MOLYBDENUM-DISULFIDE [J].
DIVIGALPITIYA, WMR ;
FRINDT, RF ;
MORRISON, SR .
SCIENCE, 1989, 246 (4928) :369-371
[7]   ELECTRONIC-PROPERTIES OF INTERCALATION COMPLEXES OF THE TRANSITION-METAL DICHALCOGENIDES [J].
FRIEND, RH ;
YOFFE, AD .
ADVANCES IN PHYSICS, 1987, 36 (01) :1-94
[8]  
GAMBLE FR, 1971, SCIENCE, V174, P4939
[9]   Layered compounds based on molybdenum disulfide and ruthenium arene complexes [J].
Golub, AS ;
Shumilova, IB ;
Zubavichus, YV ;
Jahncke, M ;
SussFink, G ;
Danot, M ;
Novikov, YN .
JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (01) :163-167
[10]   Phenanthroline intercalation into molybdenum disulfide [J].
Golub, AS ;
Shumilova, IB ;
Novikov, YN ;
Mansot, JL ;
Danot, M .
SOLID STATE IONICS, 1996, 91 (3-4) :307-314