Experimental pressure-volume-temperature data and an equation of state for trifluoroiodomethane (CF3I) in gaseous phase

被引:16
作者
Duan, YY [1 ]
Zhu, MS [1 ]
Shi, L [1 ]
Han, LZ [1 ]
机构
[1] TSING HUA UNIV,DEPT THERMAL ENGN,BEIJING 100084,PEOPLES R CHINA
关键词
PVT properties; equation of state; CF3I; trifluoroiodomethane; alternatives;
D O I
10.1016/S0378-3812(96)03227-X
中图分类号
O414.1 [热力学];
学科分类号
摘要
Some 175 pressure-volume-temperature data points in gaseous phase for trifluoroiodomethane (CF3I) have been measured using Burnett/isochoric methods. Burnett expansion measurements were made both at 353.15 K and at 323.15 K. Based on the pressure-volume relationships established both at 353.15 K and at 323.15 K isotherms, data were collected along isochores. Data along eight isochores were measured at the temperature range from 323.15 K to 393.15 K. Data along five isochores were measured at the temperature range from 278.15 K to 323.15 K. The pressure range is from 0.19 to 1.75 MPa. The maximum total temperature uncertainty in this work is estimated to be within +/- 10 mK, the maximum total pressure uncertainty in this work is estimated to be within +/- 500 Pa. The present data have been correlated with a virial equation of state. This equation has a root-mean-square deviation (RMS) deviation of 0.11% in pressure and a RMS deviation of 0.12% in density. The purity of the sample used in this work is 99.95 wt.% with 3.4 ppm of water. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:233 / 241
页数:9
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