Oxone as an inexpensive, safe, and environmentally benign oxidant for C-H bond oxygenation

被引：392

作者：

Desai, LV ^{[1
]}

Malik, HA ^{[1
]}

Sanford, MS ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 06期

关键词：

D O I：

10.1021/ol0530272

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper describes the application of peroxide-based oxidants in the Pd(OAc)(2)-catalyzed acetoxylation and etherification of arene and alkane C-H bonds. Oxone in acetic acid and/or methanol proved particularly effective, and these transformations were applied to a wide variety of substrates.

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页码：1141 / 1144

页数：4

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