A Benzoselenadiazole-Based Low Band Gap Polymer: Synthesis and Photovoltaic Application

被引：82

作者：

Zhou, Erjun ^{[1
]}

Cong, Junzi ^{[1
]}

Hashimoto, Kazuhito ^{[1
]}

Tajima, Keisuke ^{[2
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTO, Kawaguchi, Saitama 3320012, Japan

来源：

MACROMOLECULES | 2013年 / 46卷 / 03期

关键词：

DONOR-ACCEPTOR COPOLYMERS; LIGHT-EMITTING-DIODES; CONJUGATED POLYMER; SOLAR-CELLS; EFFICIENCY; ADDITIVES; SENSORS;

D O I：

10.1021/ma302596k

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel alternating copolymer with a low band gap (E-g = 1.55 eV), PBDT-DTBSe, based on benzodithiophene (BDT) and benzoselenadiazole (BSe) units with thiophene as a pi-conjugated bridge, was synthesized and characterized. When 1,8-diiodooctane was used as a solvent additive to optimize the mixing morphology, the maximum power conversion efficiency reached by a polymer solar cell based on PBDT-DTBSe/PC70BM was 5.18%, which was slightly higher than that of the benzothiadiazole (BT)-based analogue (5.01%). These results demonstrated the promising effectiveness of benzoselenadiazole as an electron-deficient unit for the design of the donor acceptor photovoltaic polymers.

引用

页码：763 / 768

页数：6

共 46 条

[1] Donor-acceptor type low band gap polymers: polysquaraines and related systems [J].

Ajayaghosh, A .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (04) :181-191

[2] Studies of highly regioregular poly(3-hexylselenophene) for photovoltaic applications [J].

Ballantyne, Amy M. ;

Chen, Lichim ;

Nelson, Jenny ;

Bradley, Donal D. C. ;

Astuti, Yeni ;

Maurano, Andrea ;

Shuttle, Christopher G. ;

Durrant, James R. ;

Heeney, Martin ;

Duffy, Warren ;

McCulloch, Iain .

ADVANCED MATERIALS, 2007, 19 (24) :4544-+

[3] Poly(diketopyrrolopyrrole-terthiophene) for Ambipolar Logic and Photovoltaics [J].

Bijleveld, Johan C. ;

Zoombelt, Arjan P. ;

Mathijssen, Simon G. J. ;

Wienk, Martijn M. ;

Turbiez, Mathieu ;

de Leeuw, Dago M. ;

Janssen, Rene A. J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (46) :16616-+

[4] Processable Low-Bandgap Polymers for Photovoltaic Applications [J].

Boudreault, Pierre-Luc T. ;

Najari, Ahmed ;

Leclerc, Mario .

CHEMISTRY OF MATERIALS, 2011, 23 (03) :456-469

[5]

Brabec CJ, 2001, ADV FUNCT MATER, V11, P15, DOI 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO

[6]

2-A

[7] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].

BURROUGHES, JH ;

BRADLEY, DDC ;

BROWN, AR ;

MARKS, RN ;

MACKAY, K ;

FRIEND, RH ;

BURN, PL ;

HOLMES, AB .

NATURE, 1990, 347 (6293) :539-541

[8] Highly sensitive biological and chemical sensors based on reversible fluorescence quenching in a conjugated polymer [J].

Chen, LH ;

McBranch, DW ;

Wang, HL ;

Helgeson, R ;

Wudl, F ;

Whitten, DG .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1999, 96 (22) :12287-12292

[9] Morphology control in polycarbazole based bulk heterojunction solar cells and its impact on device performance [J].

Chu, Ta-Ya ;

Alem, Salima ;

Tsang, Sai-Wing ;

Tse, Shing-Chi ;

Wakim, Salem ;

Lu, Jianping ;

Dennler, Gilles ;

Waller, David ;

Gaudiana, Russell ;

Tao, Ye .

APPLIED PHYSICS LETTERS, 2011, 98 (25)

[10] Conjugated polymer photovoltaic cells [J].

Coakley, KM ;

McGehee, MD .

CHEMISTRY OF MATERIALS, 2004, 16 (23) :4533-4542

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