[3]Pseudorotaxane-like complexes formed between bipyridinium dications and bis-p-xyly[26]crown-6

被引：37

作者：

Cheng, PN

Lin, CF

Liu, YH

Lai, CC

Peng, SM

Chiu, SH

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan

[2] China Med Univ Hosp, Dept Med Genet & Med Res, Taichung, Taiwan

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 03期

关键词：

D O I：

10.1021/ol052679n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The crown ether BPX26C6 forms a [3]pseudorotaxane-like complex with the N,N'-dimethyl-4,4'-bipyridinium dication both in solution and in the solid state. The facile one-pot synthesis of a [2]rotaxane from neutral precursors-BPX26C6, 4,4'-dipyridyl, and 3,5-di-tert-butylbenzyl bromide-suggests that BPX26C6 may bind to (mono)pyridinium cations in a [2]pseudorotaxane-like manner.

引用

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页码：435 / 438

页数：4

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