Four-membered group 13 metal(I) N-heterocyclic carbene analogues: Synthesis, characterization, and theoretical studies

被引：159

作者：

Jones, C

Junk, PC

Platts, JA

Stascht, A

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, Wales

[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 07期

关键词：

D O I：

10.1021/ja057967t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis, spectroscopic and structural characterization of the monomeric, four-membered group 13 metal(I) heterocycles ([:M{η2-N,N′-(Ar)NC(NCy2)N(Ar)}], M = Ga or In, Ar = C6H3Pri2-2,6) and an isomeric thallium complex are reported. Theoretical studies on these complexes, which are analogues of four-membered N-heterocyclic carbenes, suggest they should act as good σ-donor ligands. Copyright © 2006 American Chemical Society.

引用

页码：2206 / 2207

页数：2

共 21 条

[1] Aluminum alkyl complexes containing guanidinate ligands [J].