Holding onto lots of hydrogen:: A 12-hydride rhodium cluster that reversibly adds two molecules of H2

被引：36

作者：

Brayshaw, SK

Ingleson, MJ

Green, JC

Raithby, PR

Kociok-Köhn, G

McIndoe, JS

Weller, AS ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Inorgan Chem Lab, Oxford OX1 3QR, England

[3] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 42期

关键词：

cluster compounds; hydride ligands; hydrogen storage; NMR spectroscopy; structure elucidation;

D O I：

10.1002/anie.200502221

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

H Box: The clusters [Rh6(PR3)6H 12][BArF4]2 (R = cyclohexyl, iPr; see scheme, pink Rh, orange P) reversibly take up two molecules of H2 under ambient conditions (1 atm H2, 298 K) to give discrete octahedral clusters surrounded by 16 hydride ligands. (Figure Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：6875 / 6878

页数：4

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