Bandgap control through reduction of bond length alternation in bridged poly(diethienylethylene)s

被引:23
作者
Brisset, H [1 ]
Blanchard, P [1 ]
Illien, B [1 ]
Riou, A [1 ]
Roncali, J [1 ]
机构
[1] UNIV ANGERS,CNRS,UMR 6501,F-49045 ANGERS,FRANCE
关键词
GAP SEMICONDUCTING POLYMERS; CONJUGATED POLYMERS; ORGANIC POLYMERS; POLYTHIOPHENE; THIOPHENES; SYSTEMS;
D O I
10.1039/a607890g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
X-Ray structure analysis of a new rigid dithienylethylene shows that the observed reduction of the HOMO-LUMO gap results from a relaxation of bond length alternation.
引用
收藏
页码:569 / 570
页数:2
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