The preparation and characterisation of a series of group IV metallocene dithiolato complexes containing a naphthalene backbone

被引：10

作者：

Robertson, SD ^{[1
]}

Slawin, AMZ ^{[1
]}

Woollins, JD ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

POLYHEDRON | 2006年 / 25卷 / 04期

关键词：

complex; thiolates; X-ray structure; titanium; sulfur;

D O I：

10.1016/j.poly.2005.07.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of the sulfur-sulfur bond of naphtho[1,8-cd]-1,2-dithiole with 2 equivalents of Li(BEt)(3)H to give the dilithium salt followed by the addition of an equivalent of bis(pentamethyl)metallocene dichloride [(CP)(2)(MCl2)-M-*, M = Ti, Zr, Hf, Cp-* = C5Me5] (TiS2C10H6)-Ti-* (2) and (Cp)2(*)ZrS(2)C(10)H(6) (3) containing six-membered gives the sulfur bonded complexes (Cp)2 6 (1), (Cp)(2)(ZrS2C10H6)-Zr-* MS2C3 rings. The products were obtained in moderate yield as crystals and have been fully characterised and had their X-ray crystal structures determined. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：823 / 826

页数：4

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